This is the official manual for the latest Org-mode release.

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12.7.1 LaTeX export commands

C-c C-e l l     (org-latex-export-to-latex)
Export as a LaTeX file. For an Org file myfile.org, the LaTeX file will be myfile.tex. The file will be overwritten without warning.
C-c C-e l L     (org-latex-export-as-latex)
Export to a temporary buffer. Do not create a file.
C-c C-e l p     (org-latex-export-to-pdf)
Export as LaTeX and then process to PDF.
C-c C-e l o
Export as LaTeX and then process to PDF, then open the resulting PDF file.