This is the official manual for the latest Org-mode release.

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#### 12.10.10 Special blocks in LaTeX export

In LaTeX back-end, special blocks become environments of the same name. Value of :options attribute will be appended as-is to that environment's opening string. For example:

     #+BEGIN_abstract
We demonstrate how to solve the Syracuse problem.
#+END_abstract

#+ATTR_LATEX: :options [Proof of important theorem]
#+BEGIN_proof
...
Therefore, any even number greater than 2 is the sum of two primes.
#+END_proof


becomes

     \begin{abstract}
We demonstrate how to solve the Syracuse problem.
\end{abstract}

\begin{proof}[Proof of important theorem]
...
Therefore, any even number greater than 2 is the sum of two primes.
\end{proof}


If you need to insert a specific caption command, use :caption attribute. It will override standard #+CAPTION value, if any. For example:

     #+ATTR_LATEX: :caption \MyCaption{HeadingA}
#+BEGIN_proof
...
#+END_proof